全文获取类型
收费全文 | 23370篇 |
免费 | 3835篇 |
国内免费 | 2609篇 |
专业分类
化学 | 16420篇 |
晶体学 | 265篇 |
力学 | 1412篇 |
综合类 | 243篇 |
数学 | 2654篇 |
物理学 | 8820篇 |
出版年
2024年 | 12篇 |
2023年 | 492篇 |
2022年 | 496篇 |
2021年 | 677篇 |
2020年 | 981篇 |
2019年 | 893篇 |
2018年 | 744篇 |
2017年 | 716篇 |
2016年 | 1080篇 |
2015年 | 992篇 |
2014年 | 1247篇 |
2013年 | 1633篇 |
2012年 | 2070篇 |
2011年 | 2098篇 |
2010年 | 1435篇 |
2009年 | 1380篇 |
2008年 | 1552篇 |
2007年 | 1414篇 |
2006年 | 1354篇 |
2005年 | 1091篇 |
2004年 | 868篇 |
2003年 | 707篇 |
2002年 | 587篇 |
2001年 | 504篇 |
2000年 | 482篇 |
1999年 | 558篇 |
1998年 | 471篇 |
1997年 | 409篇 |
1996年 | 412篇 |
1995年 | 382篇 |
1994年 | 355篇 |
1993年 | 321篇 |
1992年 | 267篇 |
1991年 | 231篇 |
1990年 | 232篇 |
1989年 | 159篇 |
1988年 | 119篇 |
1987年 | 82篇 |
1986年 | 96篇 |
1985年 | 65篇 |
1984年 | 37篇 |
1983年 | 39篇 |
1982年 | 37篇 |
1981年 | 20篇 |
1980年 | 8篇 |
1979年 | 4篇 |
1976年 | 1篇 |
1957年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
101.
Dr. Yong-Zhi Li Gang-Ding Wang Hong-Yun Yang Prof. Lei Hou Prof. Yao-Yu Wang Prof. Zhonghua Zhu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(69):16402-16407
To develop efficient adsorbent materials for storage and separation of C2H2, an unprecedented supercage MOF, [Me2NH2]⋅[Zn3(ALP)(TDC)2.5]⋅3.5DMF⋅2 H2O ( 1 ) was constructed through medicinal molecule allopurinol (ALP) and S-containing 2,5-thiophenedicarboxylic acid (H2TDC). 1 contains a novel linear trinuclear cluster that is composed by ALP and carboxylates and forms a final uncommon 5-connected yfy topological framework. The framework possesses three types of interlinked cages decorated by rich functional sites, and reveals not only high adsorption capacity for C2H2 but also excellent selective separation for C2H2/CO2 and C2H2/CH4 at 298 K. Dynamic breakthrough experiments on C2H2/CO2 (1:1) mixture and C2H2/CH4 (1:1) mixture also demonstrated the potential of the material to separate C2H2 from CO2 or CH4 mixtures. Molecular simulations were also studied to identify the different CO2- and C2H2- binding sites in 1 , such as carboxylate groups, S atoms and carbonyl groups. 相似文献
102.
103.
104.
105.
高等教育要适应世界潮流和时代变化,本科教育须进一步提高实践教学的比重,加强理论教学与实践教学相结合,完善协同育人机制。结合学科发展和企业发展需求,中山大学化学学院与金发科技股份有限公司(简称金发科技)共同建设大学生实践教学基地。本文以中山大学-金发科技本科实践教学基地为例,探讨大学生校外实践基地建设过程中遇到的问题以及实践基地的建设内容与成果体会。 相似文献
106.
Xia Feng Junji Liu Songlin Li Yan Sun Rongjiao Zhu Lina Zhu Li Chen Yuxin Wang Xiaotao Zhang 《大学化学》2020,35(5):92-97
Remote teaching and learning have been adopted during the COVID-19 outbreak. In this particular period of time, a totally-online-teaching strategy was implemented by the teaching team of physical chemistry in Tianjin University. With the enrichment of learning resources, the optimization of the inspectors' teaching skills, as well as the elaborated managements of the whole learning process, the course has been given online successfully, though it is thought unsuitable for online teaching due to the abstruse theory and complex mathematical treatments involved in teaching. Both the central position of student and the leading role of teacher are greatly promoted in the newly developed totally-online-teaching process. The experiences obtained in this teaching process will lay great impact on teaching mode innovation in the future. 相似文献
107.
Yiping Zhang Shuqi Zhang Zirun Zhao Zhiheng Xu Songyang Wang Yuhang Zhang Maike Yang Xuanlin Yu Yaxian Zhu 《大学化学》2020,35(6):25-30
2018年和2019年小学期,厦门大学本科生"绿行之踪"社会实践队赴重庆、上海等长江流域主要城市进行社会实践活动,采集了当地的水样,测定了水样中的磷酸根含量和高锰酸盐指数,同时进行了水资源保护的宣传活动和网络问卷调查。 相似文献
108.
109.
Xiao-Ying Yu Jennifer Yao Edgar C. Buck Zihua Zhu 《Surface and interface analysis : SIA》2020,52(7):454-459
Trace analysis of nuclear materials in solid particles collected in the environment or particles in liquid slurry generated in nuclear material manufacturing processes can pinpoint elemental, organic, and isotopic signatures of nuclear fuel cycle activities and processes. Such information can support nuclear safeguards programs by increasing our ability to detect undeclared nuclear materials, routine activities for safeguarding at declared facilities, and illicit activities. However, trace radioactive material analysis in liquids and slurries is challenging using bulk approaches. For example, one drawback of sensitive analysis such as inductively coupled plasma mass spectrometry (ICP-MS) is that sample is consumed or destroyed as a result of the technical approach. We developed a vacuum compatible microfluidic interface to enable surface analysis of liquids and solid–liquid interactions using time-of-flight secondary ion mass spectrometry (ToF-SIMS). In this work, we illustrate the initial results from the analysis of liquid uranium oxide standard solutions using in situ liquid SIMS. Because the liquid SIMS analysis is almost nondestructive, the same sample can then be analyzed by other analytical techniques or saved for future reference. Consequently, multimodal analysis is possible. Our results demonstrate that in situ liquid SIMS can be used as a new approach to analyze radioactive materials in liquid and slurry forms of relevance to diverse applications. 相似文献
110.
ABSTRACTA striking feature of lyotropic chromonic liquid crystals confined in cylinder model exhibit double-twist director configurations. Evidence suggests that saddle-splay deformation is among the most important factors for the distortions of director. Previous researches limit the director to distort at a fixed plane (r-? plane) by using specific boundary conditions such as degenerate planar anchoring condition. In this work, we consider lyotropic chromonic liquid crystals confined between two coaxial cylinders with free-surface boundary conditions and Rapini-Papoular-type anchoring conditions. By using finite-difference iterative method to solve the numerical solution of Euler equation, we find that saddle-splay deformation leads to double-twist director configurations under free-surface boundary conditions, which consist of the result under degenerate planar anchoring conditions. Furthermore, at Rapini-Papoular-type anchoring conditions, saddle-splay deformation has a great influence on the director in the radial direction (r direction) and the director distorts in three-dimensional space. Remarkably, our method provides a more accurate theory basis for the measured values of saddle-splay elastic constant K24。 相似文献